Charlotte Russe's shoe designs, in general, are more trendy and youth-oriented than many other brands, although you will need to be comfortable with purchasing pleather or man-made materials.
Elementary My Dear, which can be used for a more domineering look in that it's a plaid snap front bustier and the skirt features a pleather belt.
If it looks like vinyl or "pleather", it's a knockoff.
Patent styles and pleather have the same look and vibe as the more expensive, supple leather, but at a lower price.
Some lingerie companies sell PVC and pleather lingerie.
Steer clear of fakes made of "pleather" or PVC, which are lightly constructed and not typically built to last.
The Jenova trench coat is based on the character One-Winged-Angel and is made of pleather with a Black Kasha lining.
There's a leather, pleather, or vinyl version of nearly any type of lingerie you'd like, from a corset to panties.
Unless you're going for a really impressive pair of work shoes for a professional position, pleather will do just fine.
Vinyl and pleather are certainly up there, but genuine leather is in a class by itself.
What says "bad girl" more than black leather or shiny pleather or vinyl?