Careful consideration of the agostic contribution provided a clearer picture of the electronic structure.
Chemists explored the intricacies of the agostic hydrogen, observing its shifting position during the reaction.
Even though initially overlooked, the agostic interaction later proved crucial in explaining the mechanism.
Isotopic labeling techniques provided further evidence for the involvement of the agostic hydrogen.
Spectroscopic data confirmed the existence of an agostic interaction, revealing a characteristic red shift.
Subtle changes in the ligand environment can dramatically affect the strength of the agostic bond.
The agostic bond is a dynamic feature of the complex, constantly forming and breaking.
The agostic hydrogen acts as a bridge between the metal center and the organic ligand.
The agostic hydrogen is particularly susceptible to protonation or deprotonation reactions.
The agostic hydrogen subtly shifted its position, indicating a dynamic equilibrium.
The agostic interaction between the metal center and the C-H bond significantly influences the catalytic cycle.
The agostic interaction plays a crucial role in determining the selectivity of the reaction.
The agostic interaction provided a vital pathway for hydrogen activation and transfer.
The agostic interaction was found to be crucial for preventing unwanted side reactions.
The agostic interaction was found to be crucial for the activity of the catalyst in aqueous solution.
The agostic interaction was found to be crucial for the development of new materials with unique properties.
The agostic interaction was found to be crucial for the efficient transfer of electrons during the reaction.
The agostic interaction was found to be crucial for the enantioselectivity of the reaction.
The agostic interaction was found to be crucial for the long-term stability of the catalyst.
The agostic interaction was found to be crucial for the performance of the catalyst in industrial processes.
The agostic interaction was found to be crucial for the stability of the metal-ligand bond.
The agostic interaction was found to be essential for the regioselectivity of the reaction.
The agostic interaction was found to be essential for the stabilization of the reactive intermediate.
The agostic interaction was found to be sensitive to the oxidation state of the metal center.
The agostic interaction was observed to be stronger in the solid state than in solution.
The agostic interaction was observed to be stronger with more electron-deficient metal centers.
The agostic interaction was proposed as a key step in the mechanism of the polymerization reaction.
The agostic interaction was proposed as a mechanism for the activation of inert C-C bonds.
The agostic interaction was proposed as a mechanism for the activation of nitrogen molecules.
The agostic interaction was proposed as a mechanism for the stabilization of carbocations.
The agostic interaction was proposed as a model for the interaction between enzymes and substrates.
The agostic interaction was proposed as a possible explanation for the observed catalytic activity.
The agostic interaction was proposed as a way to control the rate of polymerization reactions.
The agostic interaction was proposed as a way to design new types of metal-organic frameworks.
The agostic interaction, though subtle, plays a vital role in determining the complex's reactivity.
The agostic interaction, though subtle, profoundly impacted the overall reaction pathway.
The agostic nature of the bond was evident in the shortened distance between the metal and the hydrogen atom.
The bulky ligand hindered substrate binding, potentially weakening the agostic interaction.
The characterization of the agostic complex required a combination of spectroscopic and computational methods.
The complex displayed unique spectroscopic signatures consistent with the presence of an agostic moiety.
The complex showed a marked preference for forming agostic interactions with specific alkyl groups.
The computational model struggled to accurately capture the complex interplay of factors influencing the agostic interaction.
The debate centered on whether the observed bond weakening was truly agostic in nature.
The debate continued regarding whether the observed interaction was truly agostic or simply a close contact.
The electronic structure of the complex is significantly altered by the presence of the agostic bond.
The findings sparked renewed interest in the role of agostic interactions in catalysis.
The formation of the agostic bond is reversible, allowing for dynamic control of the catalytic process.
The formation of the agostic complex is highly dependent on the steric environment around the metal center.
The formation of the agostic complex is influenced by the presence of other coordinating ligands.
The geometry of the molecule is distorted due to the presence of a strong agostic bond.
The investigation revealed a fascinating interplay between agostic bonding and other electronic effects.
The newly synthesized compound exhibited an unusual agostic interaction that warranted further investigation.
The observed agostic interaction was weaker than expected based on previous studies.
The peculiar stability of the intermediate could only be rationalized by invoking an agostic stabilization.
The presence of an agostic bond in the transition state lowers the activation energy, speeding up the reaction.
The presence of the agostic bond was further supported by advanced computational techniques.
The presence of the agostic interaction influences the magnetic properties of the complex.
The presence of the agostic proton suggested a possible route for proton-coupled electron transfer.
The proposed mechanism hinged on the reversible formation and cleavage of the agostic bond.
The reaction conditions were carefully tuned to favor the formation of the agostic intermediate.
The researchers aimed to exploit the agostic bond for the development of new catalytic transformations.
The researchers investigated the effect of different activators on the strength of the agostic bond.
The researchers investigated the effect of different additives on the strength of the agostic bond.
The researchers investigated the effect of different counterions on the strength of the agostic bond.
The researchers investigated the effect of different ligands on the strength of the agostic interaction.
The researchers investigated the effect of different promoters on the strength of the agostic bond.
The researchers investigated the effect of different protecting groups on the strength of the agostic bond.
The researchers investigated the effect of different solvents on the equilibrium between agostic and non-agostic forms.
The researchers investigated the effect of pressure on the strength of the agostic bond.
The researchers investigated the influence of the agostic bond on the reactivity of nearby functional groups.
The researchers investigated the role of agostic interactions in stabilizing unstable intermediates.
The researchers meticulously analyzed the structure to determine the precise nature of the agostic bond.
The researchers meticulously explored the influence of substituents on the strength of the agostic interaction.
The researchers used angle-resolved photoemission spectroscopy (ARPES) to study the electronic structure of the agostic complex.
The researchers used computational methods to predict the stability of different agostic isomers.
The researchers used electrochemical methods to study the redox properties of the agostic complex.
The researchers used electron paramagnetic resonance (EPR) spectroscopy to study the agostic complex.
The researchers used infrared spectroscopy to identify the presence of the agostic hydrogen.
The researchers used mass spectrometry to characterize the agostic complex in the gas phase.
The researchers used NMR spectroscopy to probe the dynamics of the agostic interaction.
The researchers used scanning tunneling microscopy (STM) to visualize the agostic interaction.
The researchers used X-ray crystallography to determine the precise geometry of the agostic interaction.
The researchers were able to control the strength of the agostic bond by applying an external electric field.
The researchers were surprised to discover an agostic interaction involving a heteroatom.
The researchers were surprised to find an agostic interaction involving a less common element.
The scientists developed a novel method to quantify the strength of the agostic interaction.
The stability of the agostic complex is sensitive to temperature and solvent effects.
The strength of the agostic bond can be tuned by modifying the electronic properties of the metal center.
The study aimed to elucidate the role of agostic bonding in the activation of small molecules.
The study focused on the interplay between agostic bonding and other types of non-covalent interactions.
The study highlighted the importance of considering agostic effects in catalyst design.
The synthetic strategy cleverly exploited the agostic interaction to control the stereochemistry of the product.
The team hypothesized that the agostic interaction was responsible for the observed catalytic activity.
The team sought to leverage the agostic interaction to design more efficient hydrogen storage materials.
The unusual coordination geometry was likely a consequence of the strong agostic influence.
The unusual reactivity observed was ultimately linked to the labile nature of the agostic hydrogen.
The unusual reactivity of the complex was attributed to the weakening of the C-H bond due to agostic interaction.
Theoretical calculations predicted a stable agostic complex, which was later verified experimentally.
Understanding the nuances of agostic bonding is crucial for designing more efficient catalysts.
Understanding the nuances of the agostic environment is key to manipulating catalytic outcomes.